The PCxxx and CASx names are simply ratings of what the RAM is capable of running. For example, PC133 SDRAM is guaranteed by the manufacturer to run at 133MHz. This 133MHz is not a required operating speed; it merely indicates what the RAM is capable of. The same applies to the CAS rating.
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Because the PCxxx numbers are merely ratings, there are usually no problems mixing different RAM: PC100 SDRAM will operate perfectly fine together with PC133 SDRAM, using a 100MHz FSB.
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All SDRAM is backward compatible and can run at any bus speed slower than it is rated to run.
For example, a PC133 SDRAM DIMM is capable of running at 133MHz, 100MHz, and 66MHz.