Of course, none of this is even vaguely realistic. Explosives generate very large overpressures, followed by much smaller underpressures, then a smaller overpressure which decays. An explosion big enough to cause a significant amount of vacuum below the falling block would therefore also be big enough that the initial trajectory of the falling block would be upwards.
Bingo.
The "underpressure" is generally a net underpressure only, as the blast wave exits your structure and creates an overpressure outside, compared to relative ambient inside.
Gases don't oscillate (except in rare instances like superfluids). If I have high pressure at one spot, it won't "overshoot" the average, leaving a relative vacuum, then return to where it was before. Gas dynamics just don't work that way. Gas
density may drop below the average, but it will be balanced by temperature, which in turn gives you higher pressures.
If you wanted to shove a building into the ground "faster than freefall," though I can't imagine why you would, you wouldn't do it by setting off explosives in the building. You'd do it by setting off explosives
above the building. Former residents of Hiroshima and Nagasaki could tell you all about this. This gives you a net higher pressure above the roof than inside the structure, at least for a few milliseconds, and that will accelerate the building downward. Enough overpressure and you can crush a building like a soda can. Obviously, the amount of explosives required is tremendous, and there is no way this happened at the WTC.
The only other way to create a sudden partial vacuum inside a structure would be to rapidly consume a large volume of air, but to do so without generating a lot of heat. If the building was absolutely air-tight, you could simply combust all of the oxygen, and then wait a long time for the remaining lower density air to cool. Naturally, buildings aren't air-tight enough for this effect to be significant; what happens instead is fresh air is drawn into the building and continues feeding the fire. With the exception of fuel-air explosives, which generate
enormous amounts of heat, explosives contain their own oxidizers and will not exhibit this effect at all.
Theoretically you could also do it with the "Cold Bomb," an imaginary device that suddenly lowers the temperature of everything nearby. This would reduce the pressure of the air inside the building by cooling it, perhaps even liquifying it. However, the "Cold Bomb" is pure fiction.
The OP is severely mistaken in his apprehension of the term "implosion."